In the ESV, however, verse 6 continues the sense from verse 5: "5 Why should I fear in times of trouble, when the iniquity of those who cheat me surrounds me, 6 those who trust in their wealth and boast of the abundance of their riches?" The NIV is similar: "5 Why should I fear when evil days come, when wicked deceivers surround me - 6 those who trust in their wealth and boast of their great riches?"
In any case, what I noticed is that the parallelism between "their wealth" and "their riches" highlights this abundance.